山东济宁高硫煤与低硫煤煤层剖面地球化学特征研究     

姜尧发  代世峰  王西勃  赵蕾  周国庆  张丽莉  艾丽琴 《中国煤炭地质》2011,(4):1-10

运用电感耦合等离子质谱（ICP-MS）、X射线荧光光谱（XRF）、离子选择电极（ISE）、显微镜光度计和煤化学等方法,对山东济宁矿区的高硫煤（太原组16号煤层）与低硫煤（山西组3上煤层）剖面的煤岩、煤质和煤地球化学特征进行研究。高硫煤中微量元素在垂向上呈现显著的变化规律：（1）Sr含量从煤层底板到顶板呈增高趋势,而Ba含量则相反;因而Sr/Ba比值从下向上呈逐渐变大趋势（0.04～47.7）;（2）Th/U比值从下向上也呈逐渐变大趋势（0.2～37.1）;（3）As含量在煤层顶板石灰岩（26.1μg/g）、透镜状黄铁矿夹层（14.7～19.3μg/g）中较高;（4）V、Cr、Co、Ni、Cu、Pb、Zn等元素在煤层底部和顶部分层中含量较高,而在煤层中部分层中含量较低;（5）Nb、Ta、Zr、Hf、Ga等元素从煤层的底部到顶部呈逐渐降低趋势;（6）煤中稀土元素总量（REE）,除透镜状黄铁矿夹层（第2、4、11分层）外,其它分层（第1、3、5、6、7、8、9、10分层）显示从上往下逐渐增高之规律性。低硫煤中微量元素的分布和垂向变化与高硫煤明显不同：As含量在14个煤分层中都较低（1.03～3.37μg/g）,Sr/Ba比值从下向上变化不大（0.4～2.2）,各个煤分层中稀土元素总量（REE）呈现随灰份含量增高而增高的变化趋势,低硫煤与高硫煤的稀土元素分布模式差别很大。上述研究结果表明济宁矿区高硫煤与低硫煤在地球化学特征上的差别,反映了上石炭统太原组与下二叠统山西组沉积环境和聚煤条件的差别,具有指相意义;太原组16号煤层中富集的硫及有害微量元素,对环境具有潜在危害。  相似文献   

Rotation parameters of the Siberian domain and its eastern surrounding structures during different geological epochs     

V. Yu. Timofeev  A. Yu. Kazansky  D. G. Ardyukov  D. V. Metelkin  P. Yu. Gornov  N. V. Shestakov  A. V. Timofeev  G. Z. Gil’manova 《Russian Journal of Pacific Geology》2011,5(4):288-297

The motion of lithospheric blocks was analyzed in the junction zone between the Eurasian Plate and its surrounding structures. Its present-day stage was considered using GPS and seismologic data. Models of the movement of a rigid plate are considered for Eurasia. A model of Eurasia (northern part of Asia) was used to determine the rotation parameters of its southern periphery (Amur Plate) based on GPS data for the Far East (Sikhote Alin profile), and Transbaikal regions are shown as an example. A model of the Amur Plate was used to illustrate the behavior of the extension zone on its western boundary represented by the Lake Baikal depression during the Kultuk earthquake (M = 6.3, August, 27, 2008). Paleomagnetic data made it possible to determine the rotation pole of the Siberian Craton relative to its surrounding folded structures during the Mesozoic and to estimate its kinematic parameters. The permanent position of the rotation pole in the relative coordinate system since the terminal Paleozoic until the Recent indicates a constant rotation velocity of the Siberian domain within the Eurasian Plate structure.  相似文献   

Hydrogen peroxide interference in chemical oxygen demand during ozone based advanced oxidation of anaerobically digested livestock wastewater   总被引：1，自引：1，他引：0  

E. Lee M.Sc  H. Lee M.Sc.  Y. K. Kim Ph.D.  K. Sohn M.Sc.  K. Lee Ph.D. 《International Journal of Environmental Science and Technology》2011,8(2):381-388

It is known that hydrogen peroxide interferes with chemical oxygen demand analysis by consuming oxidation agents such as potassium dichromate, thus leading to overestimation of the chemical oxygen demand measurements. The objective of the study was to investigate the effects of hydrogen peroxide interference and to determine true chemical oxygen demand values on interpreting treatment performance during ozone-based advanced oxidation of livestock wastewater in which hydrogen peroxide concentration and chemical oxygen demand values are dynamically changing. According to the chemical oxygen demand monitoring data, chemical oxygen demand values were always higher than the initial chemical oxygen demand load when hydrogen peroxide was involved and the treatment performance with ozone alone or ozone/ultraviolet was better than with coupled hydrogen peroxide. The extent of overestimation was proportional to the remaining hydrogen peroxide concentration and the average overestimation ratio in livestock wastewater was in the range of 0.50～0.58 mg per 1 mg of hydrogen peroxide, depending upon the quality of the wastewater treated. True chemical oxygen demand values were estimated by correlating the extent of overestimation with the remaining hydrogen peroxide concentration during treatment. The extent of overestimation decreased to zero gradually as the amount of hydrogen peroxide also approached zero as oxidation proceeded. The corrected chemical oxygen demand values indicated underlying tendency of oxidation, which could not be seen in the original chemical oxygen demand monitoring data. Application of ozone/hydrogen peroxide was more efficient for reducing chemical oxygen demand than ozone alone, as was ozone/hydrogen peroxide/ultraviolet compared to ozone/ultraviolet. When coupled with ozone, ultraviolet irradiation was more efficient than hydrogen peroxide for decreasing chemical oxygen demand during treatment of livestock wastewater.  相似文献   

Investigation of CO₂ behavior and study on design of optimal injection into Gorae-V aquifer     

W. M. Sung  Y. S. Lee  K. H. Kim  Y. H. Jang  J. H. Lee  I. H. Yoo 《Environmental Earth Sciences》2011,64(7):1815-1821

This study presents the Bottom-hole pressure (BHP) behavior with different wettabilities and the optimal design scheme to effectively inject CO₂ into the Gorae-V aquifer. As a result, the injection rate and injectivity were increased as the wettability condition became more water-wet. However, the more wettability condition becomes water-wet, the more the ultimate CO₂ injection volume decreases. When the injectivity was 346 ton/day/Mpa at the Gorae-V aquifer, the aquifer can sustain CO₂ injection at a rate of 2,425 tons per day over this time period. A design for a complete CCS system was developed based on the existing off-shore pipeline in combination with new on-shore CO₂ transport infrastructure, and a pressure of 12.8 MPa is required at the CO₂ source to maintain this injection rate.  相似文献   

Dynamic factor analysis considering elastic boom effects in heavy lifting operations     

Kwang-Phil Park  Ju-Hwan Cha  Kyu-Yeul Lee 《Ocean Engineering》2011,38(10):1100-1113

The dynamic factor is the ratio of the maximum dynamic load to the static load acting on the wire ropes between the boom of a floating crane and a cargo. In this paper, the dynamic factor is analyzed based on dynamic simulations of a floating crane and a cargo, considering an elastic boom. For the simulation, we designed a multibody system that consists of a floating crane barge, an elastic boom, and a cargo connected to the boom through wire ropes. The dynamic equations of motion of the system are based on flexible multibody system dynamics. Six-degree-of-freedom motions are considered for the floating crane and for the cargo, and three-dimensional deformations for the elastic boom. The hydrostatic force, the hydrodynamic force, the gravitational force, and the wire rope forces are considered as external forces. The dynamic factor is obtained by numerically solving the equation. The effects of the elastic boom on heavy cargo lifting are discussed by comparing the simulation results of an elastic boom and a rigid boom.  相似文献   

Test method of cavitation erosion for marine coatings with low hardness     

Bu-Geun Paik  Ki-Sup Kim  Jong-Woo Ahn  Kyung-Rae Kim  Sang-Uk Lee 《Ocean Engineering》2011,38(13):1495-1502

Rudders of large container ships are easily affected by cavitation, which is well known to be induced by significant axial flows behind a propeller and discontinuities in the rudder. Among several methods to prevent or reduce the cavitation erosion occurred in the rudder, painting is gaining a lot of attention because it can be employed easily and cheaply. To conduct erosion tests properly, the simulation of heavily erosive cavitation is necessary. This can be generated using an inclined propeller dynamometer in the medium-size cavitation tunnel of MOERI (Maritime & Ocean Engineering Research Institute). The inclined shaft of the propeller creates strong cavitation, which occurs around the root of the propeller blade. This cavitation creates impacts through the collapsing process that are very severe, and are useful for realistic and efficient cavitation erosion tests. In the present study, the newly developed cavitation erosion test method is successfully employed to evaluate marine coatings that is mainly composed of epoxy elastomer or silicone polymer material. Silicone polymer-type paint B was found to have three times larger endurance than epoxy elastomer-type paint A.  相似文献   

Modeling and control of a 75 kW class variable liquid-column oscillator for highly efficient wave energy converter     

Byung-Hak Cho  Dong-Soon Yang  Shin-Yeol Park  Kyung-Shik Choi  Do-Hwan Lee  Seung-Hyun Byun  Hoon Jung 《Ocean Engineering》2011,38(2-3):436-443

The modeling and control of a variable liquid-column oscillator having a liquid filled U-tube with air chambers at its vertical columns are presented. As an ocean wave energy extracting device, the structure of the variable liquid-column oscillator (VLCO) is analogous to that of the tuned liquid-column damper used to suppress oscillatory motion in large structures like tall buildings and cargo ships. However, owing to an air spring effect caused by the dynamic pressure of air chambers, the amplitude of response of the VLCO becomes significantly amplified for a desired wave period. The governing equations for the motion of VLCO structure under wave excitation and the motion of liquid with an air spring effect caused by an air–liquid interaction are described by a series of nonlinear differential equations. A set of control parameters for extracting maximum power from various wave conditions is determined for the efficient operation of the VLCO. It is found that the effect of the air spring has an important role to play in making the oscillation of the VLCO match with the ocean wave. In this way, the VLCO provides the most effective mode for extracting energy from the ocean wave.  相似文献   

Occurrence and exploration of gas hydrate in the marginal seas and continental margin of the Asia and Oceania region   总被引：5，自引：0，他引：5  

Ryo Matsumoto  Byong-Jae Ryu  Sung-Rock Lee  Saulwood Lin  Shiguo Wu  Kalachand Sain  Ingo Pecher  Michael Riedel 《Marine and Petroleum Geology》2011,28(10):1751-1767

Supplies of conventional natural gas and oil are declining fast worldwide, and therefore new, unconventional forms of energy resources are needed to meet the ever-increasing demand. Amongst the many different unconventional natural resources are gas hydrates, a solid, ice-like crystalline compound of methane and water formed under specific low temperature and high pressure conditions. Gas hydrates are believed to exist in large quantities worldwide in oceanic regions of continental margins, as well as associated with permafrost regions in the Arctic. Some studies to estimate the global abundance of gas hydrate suggest that the total volume of natural gas locked up in form of gas hydrates may exceed all known conventional natural gas reserves, although large uncertainties exist in these assessments. Gas hydrates have been intensively studied in the last two decades also due to connections between climate forcing (natural and/or anthropogenic) and the potential large volumes of methane trapped in gas hydrate accumulations. The presence of gas hydrate within unconsolidated sediments of the upper few hundred meters below seafloor may also pose a geo-hazard to conventional oil and gas production. Additionally, climate variability and associated changes in pressure-temperature regimes and thus shifts in the gas hydrate stability zone may cause the occurrence of submarine slope failures.Several large-scale national gas hydrate programs exist especially in countries such as Japan, Korea, Taiwan, China, India, and New Zealand, where large demands of energy cannot be met by domestic supplies from natural resources. The past five years have seen several dedicated deep drilling expeditions and other scientific studies conducted throughout Asia and Oceania to understand gas hydrates off India, China, and Korea. This thematic set of publications is dedicated to summarize the most recent findings and results of geo-scientific studies of gas hydrates in the marginal seas and continental margin of the Asia, and Oceania region.  相似文献   

Evidence of gas hydrate from downhole logging data in the Ulleung Basin, East Sea   总被引：3，自引：0，他引：3  

Gil Young Kim  Bo Yeon Yi  Dong Geun Yoo  Byong Jae Ryu  Michael Riedel 《Marine and Petroleum Geology》2011,28(10):1979-1985

The Gas Hydrate Research and Development Organization (GHDO) of Korea successfully accomplished both coring (hydraulic piston and pressure coring) and logging (logging-while-drilling, LWD, and wireline logging) to investigate the presence of gas hydrate during the first deep drilling expedition in the Ulleung Basin, East Sea of Korea (referred to as UBGH1) in 2007. The LWD data from two sites (UBGH1-9, UBGH1-10) showed elevated electrical resistivity (>80 Ω-m) and P-wave velocity (>2000 m/s) values indicating the presence of gas hydrate. During the coring period, the richest gas hydrate accumulation was discovered at these intervals. Based on log data, the occurrence of gas hydrate is primarily controlled by the presence of fractures. The gas hydrate saturation calculated using Archie’s relation shows greater than 60% (as high as ∼90%) of the pore space, although Archie’s equation typically overestimates gas hydrate saturation in near-vertical fractures. The saturation of gas hydrate is also estimated using the modified Biot-Gassmann theory (BGTL) by Lee and Collett (2006). The saturation values estimated rom BGTL are much lower than those calculated from Archie’s equation. Based on log data, the hydrate-bearing sediment section is approximately 70 m (UBGH1-9) to 130 m (UBGH1-10) in thickness at these two sites. This was further directly confirmed by the recovery of gas hydrate samples and pore water freshening collected from deep drilling core during the expedition. LWD data also strongly support the interpretation of the seismic gas hydrate indicators (e.g., vent or chimney structures and bottom-simulating reflectors), which imply the probability of widespread gas hydrate presence in the Ulleung Basin.  相似文献   

Pre- and post-drill comparison of the Mount Elbert gas hydrate prospect, Alaska North Slope     

M.W. Lee  W.F. AgenaT.S. Collett  T.L. Inks 《Marine and Petroleum Geology》2011,28(2):578-588

In 2006, the United States Geological Survey (USGS) completed a detailed analysis and interpretation of available 2-D and 3-D seismic data, along with seismic modeling and correlation with specially processed downhole well log data for identifying potential gas hydrate accumulations on the North Slope of Alaska. A methodology was developed for identifying sub-permafrost gas hydrate prospects within the gas hydrate stability zone in the Milne Point area. The study revealed a total of 14 gas hydrate prospects in this area.In order to validate the gas hydrate prospecting protocol of the USGS and to acquire critical reservoir data needed to develop a longer-term production testing program, a stratigraphic test well was drilled at the Mount Elbert prospect in the Milne Point area in early 2007. The drilling confirmed the presence of two prominent gas-hydrate-bearing units in the Mount Elbert prospect, and high quality well logs and core data were acquired. The post-drill results indicate pre-drill predictions of the reservoir thickness and the gas-hydrate saturations based on seismic and existing well data were 90% accurate for the upper unit (hydrate unit D) and 70% accurate for the lower unit (hydrate unit C), confirming the validity of the USGS approach to gas hydrate prospecting. The Mount Elbert prospect is the first gas hydrate accumulation on the North Slope of Alaska identified primarily on the basis of seismic attribute analysis and specially processed downhole log data. Post-drill well log data enabled a better constraint of the elastic model and the development of an improved approach to the gas hydrate prospecting using seismic attributes.  相似文献